Departmental Bulletin Paper 自着火反応過程における反応中間生成物の解明(学内特別研究)

中野, 道王

A comprehensive two-dimensional gas chromatography with time of flight mass spectrometer (GC x GC - TOFMS) was employed to analyze reaction intermediates in auto-ignition process of n-C7H16/O2/Ar stoichiometric mixture. In this study, a constant volume vessel was used as a reactor. In the condition of the vessel temperature about 500K, many types of oxygen-containing hydrocarbons were detected. This result suggests that these compounds were produced by low temperature oxidation reaction process which caused negative temperature coefficient in ignition delay time.

Number of accesses :  

Other information