Journal Article Unprecedented formation of η4-(vinylketene)iron complexes from η4-(diene)iron complexes and aromatic compounds in the presence of a Lewis acid

Okauchi, Tatsuo  ,  Sata, Naoki  ,  Urakawa, Akihiro  ,  Kitamura, Mitsuru

51 ( 40 )  , pp.8454 - 8456 , 2015-05-18 , Royal Society of Chemistry
ISSN:1359-73451364-548x
NCID:AA11071130
Description
A novel and unprecedented formation of η4-(vinylketene)iron complexes from η4-(diene)iron complexes is described herein. Treatment of η4-(diene)iron complexes with a Lewis acid such as GaCl3 or AlCl3 in the presence of aromatic compounds under a CO atmosphere affords η4-(vinylketene)iron complexes via electrophilic aromatic substitution.
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