Journal Article Chiral primary amino alcohol organobase catalyst for the asymmetric Diels-Alder reaction of anthrones with maleimides

KUMAGAI, Jun  ,  OTSUKI, Teppei  ,  UMMAREDDY, Venkata Subba Reddy  ,  KOHARI, Yoshihito  ,  SEKI, Chigusa  ,  UWAI, Koji  ,  OKUYAMA, Yuko  ,  KWON, Eunsang  ,  TOKIWA, Michio  ,  TAKESHITA, Mitsuhiro  ,  NAKANO, Hiroto

26 ( 24 )  , pp.1423 - 1429 , 2015-12-31 , Elsevier
ISSN:0957-4166
NCID:AA1074621X
Description
Simple chiral TES-amino alcohol organocatalysts containing a bulkysilyl [triethylsilyl: TES] group on oxygen atom at γ-position were designed andsynthesized as new organocatalysts for the enantioselective Diels-Alder (DA) reactionof anthrones with maleimides to produce chiral hydroanthracene DA adducts (up to99% yield with up to 94% ee).
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