Journal Article Chiral primary amino alcohol organobase catalysts for the asymmetric Diels-Alder reactions of anthrones with maleimides

KUMAGAI, Jun  ,  OTSUKI, Teppei  ,  UMMAREDDY, Venkata Subba Reddy  ,  KOHARI, Yoshihito  ,  SEKI, Chigusa  ,  UWAI, Koji  ,  OKUYAMA, Yuko  ,  KWON, Eunsang  ,  TOKIWA, Michio  ,  TAKESHITA, Mitsuhiro  ,  NAKANO, Hiroto

26 ( 24 )  , pp.1423 - 1429 , 2015-12-31 , Elsevier
ISSN:0957-4166
NCID:AA1074621XAA11539844
Description
Simple chiral triethylsilyl-amino alcohol organocatalysts containing a bulky triethylsilyl group on the oxygen atom at the γ-position were designed and synthesized as new organocatalysts for enantioselective Diels–Alder reactions of anthrones with maleimides to produce chiral hydroanthracene Diels–Alder adducts in up to 99% yield and with up to 94% ee.
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