Departmental Bulletin Paper シリル基の活性化を指向した 新規アリールシラン類の合成と反応

清水, 智美

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Hydrosilanes are very useful compounds in organosilicon chemistry and synthetic organic chemistry and widely used for hydrosilylation and dehydrogenative condensation with alcohols. Here we report our synthetic study of 5−7, in which a silyl group and a dimesitylboryl group are linked to each other through biphenyl,binaphthyl, and naphthalene skeleton. Treatment of 1-halo-8-(hydrosilyl)naphthalenes 15 with catalyticamount of I2 results in silyl migration to produce 1-halo-7-(hydrosilyl)naphthalenes 16.Key Words : biphenyl, binaphthyl, naphthalene, silyl migration
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