Thesis or Dissertation Rf化アゾベンゼンを含むアクリル酸誘導体の合成とラジカル重合
SYNTHESIS AND RADICAL PORIMERIZATION OF ACRYLIC MONOMERS BEARING WITH PERFLUOROALKYLATED AZOBENZENE UNIT

角田, 佑樹  ,  TSUNODA, Yuki

(56) 2015-03-24 , 法政大学大学院理工学・工学研究科
ISSN:2187-9923
NCID:AA12677220
Description
Novel acrylic monomers bearing with perfluoroalkylated azobenzene units (FAzA, FAzEA) were synthesized and applied for the block copolymerization under ATRP conditions in TFT/DMSO at 120 ℃ for 24 h with PtBA-Br as a macroinitiator. Block copolymer PtBA-b-PFAzEA was successfully obtained and possessed the rather high molecular weight (Mn = 19300) and narrow molecular weight distribution. As expectedly, high contact angles of water and dodecane droplets were observed for PtBA-b-PFAzEA film, clearly indicating the hydrophobic and oleophobic surface formation.
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http://repo.lib.hosei.ac.jp/bitstream/10114/10719/1/13R2117.pdf

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