紀要論文 パーフルオロアルキル基を有する両親媒性トリブロック共重合体の外部環境変化応答性
SURFACE RECONSTRUCTION OF AMPHIPHILIC TRIBLOCK TERPOLYMERS BEARING WITH PERFLUOROALKYL GROUPS BY ENVIRONMENTAL CHANGES

大川, 夏芽  ,  OKAWA, Natsume

(56) 2015-03-24 , 法政大学大学院理工学・工学研究科
ISSN:2187-9923
NII書誌ID(NCID):AA12677220
内容記述
Triblock terpolymers bearing with a hydrophilic oxyethylene unit, a hydro- and oleophobic perfluoroalkyl group, and a photocrosslinkable cinnamoyl group were prepared by a sequential living anionic polymerization and quantitative functionalization reactions. Then thin polymer films were applied for the UV-irradiated photocrosslinking of the cinnamoyl groups in order to fix fluorine-cantaining segment at the top of the film surface. Contact angle and XPS measurements indicated that stabilization of the polymer film surface was successfully achieved by photocrosslinking of cinnamoyl groups. In addition, a series of tribrock terpolymers having different sequences were synthesized in order to investigate the effect of segment sequence on its surface construction.
本文を読む

http://repo.lib.hosei.ac.jp/bitstream/10114/10679/1/13R2107.pdf

このアイテムのアクセス数:  回

その他の情報