Departmental Bulletin Paper 鎖末端カルボキシ化スターポリスチレンの合成と接着性評価
SYNTHESIS AND ADHESIVE PROPERTY OF STAR-SHAPED POLYSTYRENE FUNCTIONALIZED WITH CARBOXYLIC ACID END-GROUPS

江頭, 桜太  ,  EGASHIRA, Outa

562015-03-24 , 法政大学大学院理工学・工学研究科
ISSN:21879923
NCID:AA12677220
Description
Star-shaped polystyrenes functionalized with carboxylic acid end-groups were synthesized by means of living anionic polymerization of styrene in THF initiated with a multifunctional initiator prepared by the reaction of 1,3-diisopropenylbenzene and potassium naphthalenide (KNaph) in THF at -30 ℃ followed by termination with CO2. Adhesive properties of resulting polymers were investigated by tensile test under the condition of thermo compression bonding between polystyrene and PET films. The star-shaped polystyrene showed high adhesion with PET as compared to linear polystyrene.
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http://repo.lib.hosei.ac.jp/bitstream/10114/10675/1/13R2106.pdf

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