Journal Article Phototriggered Dehydration Condensation Using an Aminocyclopropenone

Mishiro, Kenji  ,  Yushima, Yuki  ,  Kunishima, Munetaka

19 ( 18 )  , pp.4912 - 4915 , 2017-09-15 , American Chemical Society
ISSN:1523-7060
NCID:AA11347843
Description
金沢大学新学術創成研究機構
A phototriggered dehydration condensation using an aminocyclopropenone has been developed. The UV irradiation of an aminocyclopropenone generated a highly reactive ynamine in situ and the dehydration condensation of a carboxylic acid and an amine coexisting in the reaction solution smoothly proceeded to afford an amide. This reaction is completely controllable by the ON/OFF states of a UV lamp. © 2017 American Chemical Society.
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