Journal Article Photodegradation of dyes by a novel TiO2/u-RuO2/GNS nanocatalyst derived from Ru/GNS after its use as catalyst in aerial oxidation of primary alcohols (GNS = Graphene NanoSheets)

Gopiraman, Mayakrishnan  ,  Babu, Sundaram Ganesh  ,  Khatri, Zeeshan  ,  Kim, Byoung-Suhk  ,  Wei, Kai  ,  Karvembu, Ramasamy  ,  Kim, Ick Soo

115 ( 2 )  , pp.759 - 772 , 2015-08 , SPRINGER , Akadémiai Kiadó
NCID:AA12490605
Description
Ruthenium nanoparticles (RuNPs) supported on graphene nanosheets (GNS), a composite (Ru/GNS), were prepared by a dry synthesis method and were used as nanocatalysts for the aerial oxidation of various primary alcohols. Ru/GNS was highly efficient, selective, stable and heterogeneous in nature. Owing to the high stability of the used catalyst (u-Ru/GNS), it was further applied in a different catalytic system viz photocatalytic degradation, after suitable modifications. We have obtained a novel TiO2/u-RuO2/GNS catalyst from u-Ru/GNS by the sol-gel method. The catalytic activity of TiO2/u-RuO2/GNS toward the photodegradation of methyl orange (MO) and acridine orange (AO) was found to be excellent. Overall, the sustainable use of these recyclable materials (Ru/GNS and TiO2/u-RuO2/GNS) could lead to economic and environmental benefits.
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