Journal Article Synthetic studies toward aplysiasecosterol A: Construction of the novel tricyclic core

Ohyoshi, Takayuki  ,  Tano, Hikaru  ,  Akemoto, Kei  ,  Kigoshi, Hideo

58 ( 33 )  , pp.3327 - 3329 , 2017-08 , Elsevier
ISSN:0040-4039
NCID:AA00861801
Description
Aplysiasecosterol A, a 9,11-secosterol compound, has a unique tricyclic γ-diketone skeleton including a hemiacetal. The novel tricyclic core of aplysiasecosterol A is constructed by using intramolecular radical cyclization as a key step.
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