Journal Article Absolute asymmetric electrochemical polymerization

Goto, Hiromasa

96 ( 11 )  , pp.409 - 415 , 2016-12 , Taylor & Francis
ISSN:0950-0839
NCID:AA10664727
Description
Electrochemical polymerization of thiophene-based achiral monomer having azobenzene as a chromophore irradiated by circular polarized light (CPL) was carried out to obtain chiroptically active polymer film on indium-tin oxide-coated glass. Circular dichroism and optical absorption spectroscopy measurements indicate the samples show chiroptical activity. This result indicates occurrence of absolute asymmetric polymerization by laser CPL.
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