Journal Article Rhodium-Catalyzed Dehydrogenative Borylation of Aliphatic Terminal Alkenes with Pinacolborane.

Morimoto, Masao  ,  Miura, Tomoya  ,  Murakami, Masahiro

54 ( 43 )  , pp.12659 - 12663 , 2015-10-19 , wiley
Article first published online: 2 SEP 2015
Aliphatic terminal alkenes react with pinacolborane at ambient temperature to afford dehydrogenative borylation compounds as the major product when iPr-Foxap is used as the ligand with cationic rhodium(I) in the presence of norbornene, which acts as the sacrificial hydrogen acceptor. The reaction is applied to the one-pot syntheses of aldehydes and homoallylic alcohols from aliphatic terminal alkenes.

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