Journal Article Rhodium-Catalyzed Dehydrogenative Borylation of Aliphatic Terminal Alkenes with Pinacolborane.

Morimoto, Masao  ,  Miura, Tomoya  ,  Murakami, Masahiro

54 ( 43 )  , pp.12659 - 12663 , 2015-10-19 , wiley
ISSN:1433-7851
NCID:AA0052535X
Description
Article first published online: 2 SEP 2015
Aliphatic terminal alkenes react with pinacolborane at ambient temperature to afford dehydrogenative borylation compounds as the major product when iPr-Foxap is used as the ligand with cationic rhodium(I) in the presence of norbornene, which acts as the sacrificial hydrogen acceptor. The reaction is applied to the one-pot syntheses of aldehydes and homoallylic alcohols from aliphatic terminal alkenes.
Full-Text

http://repository.kulib.kyoto-u.ac.jp/dspace/bitstream/2433/203160/1/anie.201506328.pdf

Number of accesses :  

Other information