学術雑誌論文 Hydrogen-bonding catalysis of sulfonium salts

Kaneko, Shiho  ,  Kumatabara, Yusuke  ,  Shimizu, Shoichi  ,  Maruoka, Keiji  ,  Shirakawa, Seiji

53 ( 1 )  , pp.119 - 122 , 2017-01-04 , Royal Society of Chemistry
ISSN:13597345
内容記述
Although quaternary ammonium and phosphonium salts are known as important catalysts in phase-transfer catalysis, the catalytic ability of tertiary sulfonium salts has not yet been well demonstrated. Herein, we demonstrate the catalytic ability of trialkylsulfonium salts as hydrogen-bonding catalysts on the basis of the characteristic properties of the acidic α hydrogen atoms on alkylsulfonium salts.
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http://naosite.lb.nagasaki-u.ac.jp/dspace/bitstream/10069/37369/1/ChemCom53_119.pdf

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