学術雑誌論文 First total synthesis of (+)-epogymnolactam, a novel autophagy inducer

Okado, Yuji  ,  Shigetomi, Kengo  ,  Mitsuhashi, Shinya  ,  Ubukata, Makoto

68 ( 12 )  , pp.721 - 724 , 2015-12 , 日本抗生物質学術協議会(Japan Antibiotics Research Association)
ISSN:0021-8820
NII書誌ID(NCID):AA0069330X
内容記述
A novel autophagy inducer, (+)-epogymnolactam (1), was first synthesized from cis-4-benzyloxy-2-butene-1-ol (2) in eight steps. A reliable preparation of optically pure epoxy alcohol (+)-3 from monobenzyl derivative (2) was established by a tandem strategy, Sharpless epoxidation/lipase kinetic resolution.
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http://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/62305/1/71886%28Ubukata%ef%bc%89pdf.pdf

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