学術雑誌論文 Copper(I)-catalyzed carbon-halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties

Iwamoto, Hiroaki  ,  Kubota, Koji  ,  Yamamoto, Eiji  ,  Ito, Hajime

51 ( 47 )  , pp.9655 - 9658 , 2015-05-06 , The Royal Society of Chemistry
ISSN:1359-7345
内容記述
The selective boryl substitution of alkyl halides bearing terminal C=C double bonds has been achieved using a copper(I)/tricyclohexylphosphine or copper(I)/o-diphenylphosphinophenol catalyst. This reaction represents a useful complementary approach to conventional procedures for the hydroboration of C=C double bonds or the borylative cyclization of alkyl halides bearing terminal alkenes.
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http://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/61453/1/boryl%20substitution_HUSCAP.pdf

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