学術雑誌論文 Dehydration of sorbitol to isosorbide over H-beta zeolites with high Si/Al ratios

Kobayashi, Hirokazu  ,  Yokoyama, Haruka  ,  Feng, Bo  ,  Fukuoka, Atsushi

17 ( 5 )  , pp.2732 - 2735 , 2015-05 , The Royal Society of Chemistry
ISSN:1463-9262
内容記述
Conversion of sorbitol to isosorbide by heterogeneous catalysts is a challenge in biorefinery. Herein, H-beta zeolites with specific Si/Al ratios uniquely give isosorbide in up to 76% yield under mild conditions. Mechanistic study has suggested that acid sites on hydrophobic internal surface are active for this reaction.
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http://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/61446/2/GreenChem17_2732Suppl.pdf

http://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/61446/1/GreenChem17_2732.pdf

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