学術雑誌論文 Substituent Effects at the 5-Position of 3-[Bis(pyridine-2-ylmethyl)amino]-BODIPY Cation Sensor Used for Ratiometric Quantification of Cu2+

Hafuka, Akira  ,  Kando, Ryosuke  ,  Ohya, Kohei  ,  Yamada, Koji  ,  Okabe, Satoshi  ,  Satoh, Hisashi

88 ( 3 )  , pp.447 - 454 , 2015-03-15 , 日本化学会(Chemical Society of Japan)
ISSN:0009-2673
内容記述
In this paper, we investigated the effects of substitution at the 5-position of an asymmetric BODIPY cation sensor to tune its spectroscopic, photophysical, and cation-sensing properties. We introduced substituent groups with differing electron density at the 5-position of 3-[bis(pyridine-2-ylmethyl)amino]-BODIPY, which contains a cation recognition moiety at the 3-position of the BODIPY core, to develop four sensors which all exhibited distinctive ratiometric spectral changes in the presence of Cu2+. Aromatic substitution increased the Stokes shift. Substitution with the electron-withdrawing sulfonylphenyl group resulted in the highest fluorescence quantum yield, largest absorption coefficient, and largest spectral shift in the presence of Cu2+. The sulfonylphenyl-substituted sensor also exhibited excellent selectivity for Cu2+.
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http://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/58602/1/Hafuka%202015%20BCSJ%2088%20447.pdf

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