学術雑誌論文 Enhancing the low-energy absorption band and charge mobility of antiaromatic Ni^II norcorroles by their substituent effects

Yoshida, Takuya  ,  Sakamaki, Daisuke  ,  Seki, Shu  ,  Shinokubo, Hiroshi

53 ( 6 )  , pp.1112 - 1115 , 2017-01-18 , Royal Society of Chemistry
ISSN:1359-7345
内容記述
Dissymmetrical substitution of norcorrole enables the preparation of various norcorrole derivatives as air- and moisture-stable species. Intramolecular charge transfer interactions between electron-donating substituents and the norcorrole core in these norcorroles significantly enhanced their low-energy absorption bands, which were forbidden in symmetrical NiII dimesitylnorcorrole.
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